第 36 节
作者:辩论      更新:2021-02-27 01:30      字数:9321
  ink。
  〃2d。 The application of a thin layer of gum; of
  starch; or farina; of gelatine; or fish…glue; with a
  view of sizing certain parts of the paper; or of
  causing certain bodies to adhere to it momentarily;
  is detected by an action similar to that which
  shows paper to have lately been wetted by the contact
  of liquids。
  〃3d。 The heterogeneousness of the pulp of the
  papers; and the kind of size with which they are
  impregnated; lead to differences in the results
  which are observed with the same chemical reagents。
  We shall now examine each of these propositions;
  and describe the means which we have
  employed in endeavoring to solve questions of so
  high a degree of interest。
  〃1st。 The homogeneousness of sized paper not
  partially altered by the contact of liquids (water;
  alcohol; salt…water; vinegar; saliva; tears; urine;
  acid salts; and alkaline salts) is demonstrated by
  the uniform coloration which this surface takes on
  being exposed; if not wholly; at least in various
  parts; to the action of the vapor of iodine disengaged
  at the ordinary temperature from a flask
  containing a portion of the metalloid。 When the
  surface of paper not stained by any of the above
  mentioned liquids is exposed to the action of this
  vapor for three or four minutes in a room the temperature
  of which is about 60 degrees F。; a uniform yellowish;
  or light…brownish yellow; coloration is noticed
  on the whole extent exposed to the vapor of
  iodine; in the contrary case; the surface which has
  been moistened; and afterwards dried in the open
  air; is perfectly distinguished by a different and
  well circumscribed tint。 On the papers into which
  paste starch and resin have been introduced; the
  stains present such delicate reactions that we may
  sometimes distinguish by their color the portion of
  paper which has been moistened with alcohol from
  that which has been moistened with water。 The
  stain produced by alcohol takes a bistre…yellow
  tint; that formed by water is colored of a more or
  less deep violet blue; the desiccation having been
  effected at the ordinary temperature。 For the
  stains occasioned on these same papers by other
  aqueous liquids; the tint; apart from its intensity;
  resembles that of the stains of pure water。 The
  feeble or dilute acids act like water on the surface
  of the same paper containing starch in its paste;
  but the concentrated mineral acids; by altering
  more or less the substances which enter into the
  composition of the latter; give test to the stains
  which present differences。 We are always able
  to recognize by the action of the vapor of iodine
  the parts of the paper which have been put in
  contact with chemical agents; the energy of which
  has been arrested by washing in cold water。 We
  are able; on several ancient deeds; written on
  stamped paper; and a few words of which had
  been removed by us with chemical agents; to
  recognize the places where their action was exerted;
  to see and to measure the extent which they occupied
  on the surface of the paper。
  〃The testing of a paper with the vapor of
  iodine will present this double advantage over the
  methods hitherto practiced for detecting falsifications
  in writings; that it points out at once the
  place in the paper in which any alteration may be
  suspected; and that; on the other hand; it enables
  us to act afterwards with the reagents proper for
  causing the reappearance of the traces of ink; when
  that is possible。 If the means which we now propose
  cannot always make the former writing
  appear; they demonstrate the places where the
  alterations must have been made; when; however;
  the want of uniformity presented by the surface
  of the paper is not explained by any circumstance。
  This proof becomes; therefore; a weapon which
  the guilty person cannot avoid。 But might not
  the presence of a stain; or several stains; developed
  by the vapor of iodine; in different parts of a public
  or private deed; give rise to a suspicion; where
  these stains have; perhaps; been occasioned by the
  spilling of some liquid on the surface of the paper?
  and would it not be rash and unjust to raise an
  accusation from such a fact? There would indeed
  be great temerity in drawing such a conclusion
  from a fortuitous circumstance; but the inference
  which may be drawn from the place occupied by
  these stains on the surface of the paper; from the
  more or less significant words found in those places;
  would not permit an accusation to be so lightly
  brought; where simple reasoning would be sufficient
  to destroy its basis。 Besides; the subsequent reactions
  which would be made would certainly never
  revive words formerly written and effaced; whilst
  the latter effects may be often produced; more or
  less visibly; on those parts of the paper on which
  falsification has been practiced; figures or words
  being substituted for other figures or words。
  〃2d。 The applications made to the surface of
  a sheet of paper; with a view of covering it again
  at certain parts with a fine layer of gum; gelatine;
  starch or flour paste; or in other places to cause
  other sheets of paper to adhere; may be recognized
  not only by the reflection of light falling upon the
  paper inclined at a certain degree of obliquity; and
  by the transmission of light through the paper;
  but also by the varying action which the vapor of
  iodine exerts on the surface which is not homogeneous。
  Papers containing starch and resin are
  more powerfully acted upon by this vapor than
  papers of a less complex composition。 Both in
  the parts covered with starch; or paste flour; are
  colored in a few minutes of a violet blue; but
  with starched papers alone a more intense coloration
  is manifest on the places covered again with a
  thin layer of gum arabic; size or gelatine。 By
  looking; then; on the surface of the paper; held
  somewhat obliquely to incidental light; we distinguish
  clearly; by their different aspects; the parts
  on which these various substances have been
  applied。 The vapor of iodine; in condensing at
  the ordinary temperature on the surface of the
  papers to which any kind of size has been applied
  in various places; produces differences which are
  most commonly well recognized by the greater or
  less transparence of the paste of the paper。
  3d。 The heterogeneousness of the pulp of the
  various papers of commerce; and the nature of
  the size with which they are penetrated; cause
  differences; either in the coloration which the surface
  of these papers takes when exposed to the
  vapor of iodine; or in the tint which is manifested
  in the portions of the size deposited in certain
  portions of that surface; thus; papers with starched
  pulp generally turn brown; or blue; according to
  the amount of water that remains in their interstices;
  other papers turn yellow only under the
  influence of the vapor of iodine; and the parts
  which have received superficially a layer of another
  agglutinative body resist this action for a certain
  time; and are distinguished from the parts of the
  paper which are not covered with it。〃
  My own investigations confirm to a great extent
  the value of these experiments and the accuracy of
  the deductions; in so far as they relate to 〃linen〃
  paper; but they do not always obtain when made in
  connection with paper of inferior grades。
  It is also true that dry paper is affected differently
  under the influence of the vapor of iodine; as would
  be paper which had been moistened and then dried;
  but the part which had been moist assumes the color
  of blue…violet; while unaltered paper assumes a yellow…
  brown color。 Even when the paper thus treated is
  moistened all over with water; there will be a difference;
  for those parts which had been before moistened;
  will appear a dark violet…blue; while the other parts
  will show a plain blue coloration。
  In cases where pencil writing has been removed
  with a soft rubber or fresh bread; the parts thus
  erased will assume; when subjected to iodine fumes; a
  brown color trending towards violet and much darker
  than the undisturbed portions of the paper。 Lines
  impressed upon paper with a 〃stylus;〃 a glass or
  ordinary dry pen; can be made visible by the fumes of
  iodine; the lines showing with a stronger coloration
  than the surrounding paper。
  CHAPTER XX。
  FUGITIVE INK。
  SOME OBSERVATIONS ABOUT 〃ADDED〃 COLOR TO INK
  INVENTION OF COAL TAR COLORSCHRONOLOGICAL HISTORY
  OF THE 〃ANILINES〃 EMPLOYED AS INKOTHER
  SUBSTANCES USED FOR THE SAME PURPOSE。
  THE term 〃added color;〃 as applied to ink; is the
  popular phraseology for a multitude of materials
  which have been more or less utilized for a period of
  centuries; in adulterating and coloring ink。 In olden
  times they were introduced into ink with an honest
  belief that it would also improve and ensure its lasting
  qualities; but latterly more often to cheapen the
  cost of