第 34 节
作者:辩论      更新:2021-02-27 01:30      字数:9322
  Ink marks made with a compound consisting of the
  combination of iron and an infusion of galls or its
  equivalent (a tanno…gallate of iron ink); as treated
  with certain chemicals; change from a compound with
  color to a chemical compound; with no color。 Nothing
  has in fact been absolutely removed or eradicated;
  but it is a mere change of form; a sort of re…arrangement
  of the particles; the ingredients which formed
  the original color being still present; but in such a
  condition that they are invisible to the eye。 A restoration
  of the invisible ink marks so that they can
  be observed; becomes possible by the use of chemical
  reagents and is the reverse of the one of erasure or
  bleaching; and changes the constituents again into a
  compound which has color from the one which had
  none。 It does; not; however; reproduce the exact composition
  originally existing。 Such a reagent simply
  goes to the basis of the material as first used; takes
  up what was left and reforms the particles sufficiently
  to make them abundantly recognizable。 An apt
  illustration of these chemical changes of color is found
  in what is known as the phenolphtalein test solution;
  which is colored deep purplish…red by alkali hydrates
  or carbonates; and then by the addition of an acid
  rendered colorless; to be again reddened by an over…
  plus of the alkali and so on ad infinitum。
  A popular material for the purpose of making
  chemical erasures is chlorinated lime or soda; which
  becomes more active by first touching the ink mark
  to be removed with a one half strength solution of
  acetic acid; this hastens the liberation of chlorine
  gas; THE active agent which causes the 〃bleaching〃
  to take place。 Hydrogen peroxide; also a bleaching
  compound; is less rapid in its action than chlorinate
  of soda; the same may be said of combinations of
  oxalic and sulphurous acids。
  The most effective re…agent for the restoration of a
  chemically 〃bleached〃 iron ink mark is the sulphide
  or sulphuret of ammonia (it has several names)。 This
  penetrating chemical blackens metals or their salts;
  whether visible or not; if brought together。 It must
  not be used by direct contact; the best and safest
  plan being to place a quantity in a small saucer; to be
  set on the floor of a closed box; to fasten to the box
  lid the specimen to be operated on; in this way the
  restoration is due to the fumes of the chemical and a
  possible danger of destruction of the specimen much
  lessened; especially if the marks are very light or delicate
  ones。 The restoration of color under particular
  conditions may also be obtained by treatment with
  tannic acid; potassium ferro…cyanide (acidulated) or a
  weak solution of an infusion of galls。
  CHAPTER XVIII。
  INK CHEMISTRY。
  SOME OBSERVATIONS AS TO CHEMICAL EXAMINATION OF
  INK MARKS BY ALLENERASING OF INKS BY CHEMICAL
  MEANSAPPROVED CHEMICAL TESTS IN THE
  ASCERTAINMENT OF INK CONSTITUENTS。
  A COMPILATION of the methods of Robertson;
  W。 Thompson (Lord Kelvin); Irvine; Wislar; Hoffman
  and others; relative to the chemical examination of ink
  marks; is to be found in 〃Allen's Commercial Organic
  Analysis。〃 Their experiments; however; date back
  many years ago; a few of them before the time of the
  use of the 〃anilines〃 for added color。 The so…called
  〃alizarin〃 ink referred to has now become obsolete。
  The following is the citation in part:
  〃In chemico…legal cases it is sometimes of
  importance to ascertain the nature of the ink used;
  to compare it with specimens of writing of known
  history; and to ascertain the relative ages of the
  writings。 A minute inspection should first be
  made with a magnifying power of about 10 diameters;
  and any peculiarities of color; lustre; shade;
  etc。; duly noted; and where lines cross each other
  which lie uppermost。 The examination is often
  facilitated by moistening the paper with benzine
  or petroleum spirit; whereby it is rendered semi…
  transparent。 The use of alcohol or water is inadmissible。
  〃Valuable information is often obtainable by
  treating writing or other ink…marks with reagents。
  Some inks are affected much more rapidly than
  others; though the rate of change depends greatly
  on the age of the writing。 Normal oxalic acid (63
  grammes per litre); or hydrochloric acid of
  corresponding strength; should be applied to a part of
  the ink marked with a feather or camel…hair brush
  (or the writing may be traced over with a quill
  pen); and the action observed by means of a lens;
  the reagent being allowed to dry on the paper。
  Recent writing (one or two days old) in gallic inks
  is changed by one application of oxalic acid to a
  light gray; or by hydrochloric acid to yellow。
  Older stains resist longer; in proportion to their
  age; and a deeper color remains。 Log…wood ink
  marks are mostly reddened by oxalic acid; and
  alizarin marks become bluish; but aniline inks
  are unaffected。 With hydrochloric acid; logwood
  ink marks turn reddish or reddish…gray; alizarin
  marks greenish; and aniline ink marks reddish or
  brownish…gray。 The treatment with acid should
  be followed by exposure to ammonia vapors; or
  blotting paper wet with ammonia may be applied。
  Thus treated; marks in logwood ink turn dark
  violet or violet…black。 The age of ink marks very
  greatly affects the rate of their fading when treated
  with dilute ammonia; the old marks being more
  refractory。 The behavior of ink marks when
  treated with solution of bleaching powder is often
  characteristic; the older writings resisting longer;
  but unless the reagent be extremely dilute; writings
  of all ages are removed almost simultaneously。
  Hydrogen peroxide acts more slowly than bleaching
  solution; but gives more definite results。 After
  bleaching the mark by either reagent; the iron of
  the ink remains mordanted on the paper; and the
  mark may be restored by treatment with a dilute
  solution of galls; tannic acid; or acidulated ferro…
  cyanide。 The same reagents may be used for restoring
  writing which has been faded from age
  alone。
  〃When ink marks have been erased or discharged
  by chemical means; traces of the treatment
  are often recognizable。 After effecting the erasure
  the spot is often rubbed over with a powdered alum
  or gum sandarac; or coated with gelatin or size。
  The bleaching agents most likely to have been
  used are oxalic; citric; or hydrochloric acid; bleaching
  powder solution; or acid sulphite of sodium。
  Moistened litmus paper will indicate the presence
  of a free acid; and in some cases treatment with
  ammonia fumes will restore the color。 The presence
  of calcium; chlorides; or sulphates in the
  water in which the paper is soaked will afford some
  indication of bleaching powder or a sulphite having
  been used。 Potassium ferro…cyanide will detect
  any iron remaining in the paper。 Exposure to
  iodine vapor often affords evidence of chemical
  treatment; and other methods of examination
  readily suggest themselves。〃
  M。 Piesse; in the Scientific American; is authority
  for a method of removing ink; found on 〃patent〃
  check paper:
  〃Alternately wash the paper with a camel's…
  hair brush dipped in a solution of cyanide of
  potassium and oxalic acid; then when the ink has
  disappeared wash the paper with pure water。〃
  Inks of the tanno…gallate of iron family; whether
  containing 〃added〃 color or not; can be more or less
  〃erased〃 by chlorinate of lime or soda; in the
  presence of a weak acid。 These chemicals do not;
  however; materially affect the prussian blue inks;
  which require solutions of hydrate of potash or soda。
  Real indigo can be removed by chloroform; morphine
  or an aniline salt (indigo and aniline both owe their
  names to the same Portuguese source); which possess
  the rare property of dissolving pure indigo。 Such
  combination; if refractory in the presence of permanganate
  of potash with sulphuric acid; must be followed
  by an application of sulphurous acid。 In like
  manner; inks composed of by…products of coal tar; can
  be effectively treated; when irradicable with plain
  water or soap and water。
  The erasure and removal of most inks from paper
  can be accomplished by the application of the chemicals
  heretofore enumerated。 The requirements in
  this direction of some inks; however; though of rare
  occurrence; are to be met by the employment of other
  and particular reagents。
  Many of the tests specified in the Allen citation to
  determine the character of ink constituents; if made
  alone are practically valueless; because the same behavior
  occurs with different materials employed in the
  admixture of ink。 To avoid error in judgment the
  operator should verify if possible by confirmatory
  tests。 Thus; in the one for logwood; sulphurous acid
  will cause a logwood ink mark to turn yellow; mercuric
  chloride; orange; tartar…emetic; red; and if the
  marks are faded ones; solutions of sulphate of iron
  or b