第 33 节
作者:辩论      更新:2021-02-27 01:30      字数:9320
  is discovered for the carbon which forms nearly the
  whole of its composition; at which time THE perfect
  ink can be said to have been discovered。
  CHAPTER XVII。
  INK PHENOMENA。
  CONDITION OF INK WHEN FIRST PLACED ON PAPERITS
  METAMORPHOSIS AND AFFINITIESIGNORANCE OF THE
  FORGER AS TO ITS ORIGINAL ENVIRONMENTTREATMENT
  OF OLD INK MARKSHOW PAPER MAY DISCOLOR
  INKTHE USES OF ACID IN INKVEHICLES
  TO HOLD INK PARTICLES AND PRESERVE THEMINKS
  FIVE CENTURIES OLD DO PRESERVE THEIR
  GLOSSSOME CAUSES OF INK DISINTEGRATIONWHEN
  INK BECOMES IRRESPONSIVE TO THE ELEMENTS
  DEMONSTRATED TRUTHS ABOUT INK CONSTITUENTS AND
  COLOR PHENOMENANATURAL EVOLUTION OF AN
  INK MARKLENGTH OF TIME REQUIRED TO BECOME
  BLACKFIRST INDICATIONS OF AGEDISAPPEARANCE
  OF INK QUALITIESARTIFICIAL AGING OF INKTESTS
  FOR IT AND HOW TO CONFIRM THEMBLEACHING AND
  REMOVAL OF INK FROM PAPER CRIMINALLY CONSIDERED
  CHEMISTRY OF SUCH MARKSTHEIR RESTORATION
  VARIATIONS IN METHODS WHICH CAN BE
  EMPLOYED。
  ALL inks when first placed on paper are of course
  in a fluid state。 Gradual evaporation of moisture
  causes a change not only in color but in the case of
  the iron and gall inks; in their chemical constitution;
  being immediately affected by their environment;
  whether due to the character of the paper on which
  they rest; the kind or condition of the pen used; or
  most important of all; the elements。 Those who use the
  black inks and chemical writing fluids will have noticed
  these characteristics。 The pale brown; blue or green
  as first written; and the gradual change after a short
  period to an approaching blackness; are reactions due
  largely to atmospheric conditions; the oxygen uniting
  with that for which it has affinity and instantly
  beginning with TIME to make its march; producing
  natural phenomena; which can be only superficially
  imitated but never exactly reproduced。 When we
  further take into consideration that the forger cannot
  always know of the circumstances which surround
  the placing of original ink on paper and that be cannot
  manufacture the TIME which has already elapsed;
  it is not strange that attempted fraud can often be
  made evident and complete demonstrations given of
  the methods employed。
  With the passage of time; the particles in some
  inks which are held together on the paper by gummy
  vehicles; commence to disintegrate and change from
  intense black to the brown color of iron rust; the
  〃added〃 color which of itself is fugitive in character;
  soon departs; the vegetable astringent separating
  from the iron salt decays gradually and disappears
  and finally terminates in a mere stain or dust mark
  which can be blown off the paper。 Sometimes; the
  written surface of such paper can be treated by carefully
  moistening it with a decoction of nut…galls or its
  equivalent in the presence of a weak acid; then if any
  iron be present; a measurable degree of restoration of
  color will ensue and remain for a short period。
  Again; the discoloration of an iron ink may be due to
  the character of the paper; if of the cheaper grades
  and the bleaching compounds employed in their
  manufacture are not thoroughly washed out; then the
  ink not only begins to absorb oxygen from the
  atmosphere but the chlorine in the paper attacks it
  and the process of destruction is thereby hastened。
  The introduction of acid into ink has two purposes;
  one to secure more limpidity; and the other to cause
  it to penetrate the paper and in this way bind
  together the constituent particles of both ink and
  paper。 Most of the chemical writing fluids of this
  decade carry a superabundance of acid in their
  composition; which in time will burn through the paper
  and ultimately destroy it。
  All tanno…gallate of iron inks require some vehicle
  to hold their particles in a state of suspension; otherwise
  there would be precipitation and such an ink
  could not be used。 To meet this requirement a
  variety of gums are employed by manufacturers;
  gum acacia being the principal one。 Its purpose is
  threefoldas before stated; to hold the ink particles
  in suspensionto prevent the ink from flowing too
  rapidly; and after drying WITHOUT blotting; to act as
  an envelope to encase the now fixed ink and prevent
  or interfere with its absorption of an excess of oxygen。
  The longer these latter conditions obtain the longer
  will the ink retain its pristineness; its durability and
  permanence。 The 〃time proved〃 ink…written specimens
  of five hundred years or more ago which continue
  to retain their original intense black color and
  〃glossy〃 appearance; do not; however; yield any evidence
  of the use of vegetable gums in their composition。
  Where such instances have been noticed the gloss is
  invariably missing。 But; where ANY gloss is present;
  it was and is because of the employment of isinglass
  (fish…glue) as the vehicle to hold the ancient ink
  particles。
  Hence the variations of color seen in ancient paper
  writings; as already stated; were due not only to possible
  imperfect admixtures of the component parts of
  the inks; but to the use of vegetable gums in their
  preparation。 In the course of time these have been
  absorbed by moisture which hastened disintegration;
  causing a gradual disappearance of their original blackness
  and gloss and finally a return to the rusty color
  of oxidized iron。
  It therefore follows; my observations and deductions
  being correct; the older a writing made with
  tanno…gallate of iron ink; where isinglass is the binder;
  and which has not been 〃blotted;〃 the harder and
  more impervious and irresponsive it becomes to the
  action of the natural elements or of chemical reagents。
  The truths demonstrated in this proposition cannot
  be denied。 They fortify as certain that a properly
  proportioned mixture in water of an infusion of nut…
  galls or gallo…tannic acid and sulphate of iron; with
  isinglass as the vehicle to bold the particles in a state
  of suspension; if written with on good paper and allowed
  to dry without blotting; in a short time becomes
  encased or enveloped in such vehicle; which is thereby
  rendered substantially insoluble and absolutely
  prevents any extensive oxidation。 Also; as a further
  consequent result; there is chemically created an
  unchangeable and continuing black color more permanent
  and durable than the substance on which it appears。
  With a sample of standard commercial chemical
  writing fluid; write on 〃linen〃 paper without blotting
  it; in thirty hours; if exposed to the air and
  from three to five days if kept from it; the writing
  should have assumed a color bordering on black; it
  becomes black at the end of a month under any conditions;
  and so continues for a period of about five
  or six years; when if examined under a lens of the
  magnification of ten diameters; there will be a noticeable
  discoloration of the sides or pen tracks which
  slowly spreads during a continuing period of from ten
  to fifteen years; until the entire pen marks are of a
  rusty brown tint。 A species of disintegration and
  decay is now progressing and when approximately
  forty years of age; has destroyed all ink qualities。
  If; however; 〃chemical writing fluid〃 is first treated
  by exposure to the fumes of an ammoniacal gas; a
  〃browning〃 of the ink occurs; not only of the pen
  tracks but of the entire ink mark。 If examined now
  with a lens; the ink is found to be thin enough to permit
  the fibre of the paper to be seen through it; thus indicating
  artificial age。 Furthermore; if a 20 per cent
  strength of hydrochloric acid be applied; the 〃added〃
  color (usually a blue one) is restored to ITS original
  hue; alike experiment on 〃time〃 aged ink gives
  only the yellow brown tint of pure gall and iron
  combinations; the 〃added〃 color having departed caused
  by its fugitive characteristics。 Again; if a solution of
  chlorinate of lime or soda be applied; the ink mark
  is instantly bleached; where in the case of honest old
  ink marks; it takes considerable time to even approximate
  a like result。
  To confirm the chemical tests which may be employed
  in the determination of the artificial aging of
  ink marks; photographs made by permitting light to
  transmit through the paper and to interfere with its
  rays by filtering them through a 〃color〃 screen containing
  orange and some green; will indicate the presence
  of a fugitive substance in the ink; usually the
  〃added〃 color employed in its manufacture。
  The process of bleaching or 〃removal〃 of ink marks
  from paper is frequently employed in the attempted
  eradication of words or figures and the substitution
  of others on monetary instruments; commonly called
  〃raising。〃 Its purpose is usually a criminal one and
  some observations as to the modus operandi and its
  chemistry are not out of place here。
  Ink marks made with a compound consisting of the
  combination of iron and an infusion of galls or its